Highly efficient telluride electrocatalysts for use as Pt-free counter electrodes in dye-sensitized solar cells.
نویسندگان
چکیده
Two transition metal tellurides, CoTe and NiTe2, were synthesized and for the first time employed as the counter electrodes (CEs) with high catalytic activity for reduction of I3(-) in dye-sensitized solar cells (DSCs). Using CoTe and NiTe2-based CEs, photoelectric conversion efficiencies (PCEs) of 6.92% and 7.21% were achieved for DSCs, respectively, comparable to that of 7.04% achieved when using a Pt-based CE. The results indicated that, serving as a CE in DSCs, telluride could be a cost-effective and efficient alternative to the noble metal Pt.
منابع مشابه
Recent development of carbon nanotubes materials as counter electrode for dye-sensitized solar cells
Dye-sensitized solar cells present promising low-cost alternatives to the conventional Silicon (Si)-based solar cells. The counter electrode generally consists of Pt deposited onto FTO plate. Since Pt is rare and expensive metal, nanostructured carbonaceous materials have been widely investigated as a promising alternative to replace it. Carbon nanotubes have shown significant properties such...
متن کاملTransition metal selenides as efficient counter-electrode materials for dye-sensitized solar cells.
Exploiting an alternative of the Pt-based counter-electrode materials for the triiodide reduction reaction has become a major interest in the fundamental research of dye-sensitized solar cells. Transition-metal selenides have recently been demonstrated as promising non-precious metal electrocatalysts for the triiodide reduction reaction. Herein, we prepared a series of transition-metal selenide...
متن کاملHighly ordered TiN nanotube arrays as counter electrodes for dye-sensitized solar cells.
TiN nanotube arrays, prepared by the anodization of metallic Ti foil substrate and subsequent simple nitridation in an ammonia atmosphere, were investigated as low-cost counter electrodes in dye-sensitized solar cells for the first time. It is found that the highly ordered TiN nanotube arrays on the metallic Ti foil substrate show an excellent performance, comparable with typical Pt counter ele...
متن کاملEmploying electrostatic self-assembly of tailored nickel sulfide nanoparticles for quasi-solid-state dye-sensitized solar cells with Pt-free counter electrodes.
A low cost, low-temperature processable, highly efficient nickel sulfide counter electrode is demonstrated. Using the tailored, preformed nickel sulfide nanoparticles and electrostatic self-assembly, a novel counter electrode was fabricated that exceeded the efficiency of a conventional Pt-based cell.
متن کاملPlatinum-Free Counter Electrode Comprised of Metal-Organic-Framework (MOF)-Derived Cobalt Sulfide Nanoparticles for Efficient Dye-Sensitized Solar Cells (DSSCs)
We fabricated a highly efficient (with a solar-to-electricity conversion efficiency (η) of 8.1%) Pt-free dye-sensitized solar cell (DSSC). The counter electrode was made of cobalt sulfide (CoS) nanoparticles synthesized via surfactant-assisted preparation of a metal organic framework, ZIF-67, with controllable particle sizes (50 to 320 nm) and subsequent oxidation and sulfide conversion. In con...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 49 86 شماره
صفحات -
تاریخ انتشار 2013